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Alliance War needs annoying champs to increase the chance to get more kills, but do remember that you should not place one particular champ on many nodes, else your opponent may win because of the increased diversity point. So take care of diversity if you really care about winning.
Note About Defender Tactics: Defender Tactics have a very important role in winning if you are Tier 1 to Tier 5 ally. Learn about them and the champions that can benefit from Defender Tactics.

AW Boss Suggestion

DefendersDefenders
Thing (High Sigs)Apocalypse
Doctor Doom (High Sigs)Domino (High Sigs)
Mojo (Duped)Annihilus (Duped)
Nick Fury (Duped)Korg (Duped)
Wolverine (Weapon X) (High Sigs)Peni Parker
Kitty Pryde (Duped)Mister Negative
BishopAmerica Chavez
SersiHulking

Alliance War Defender Suggestion – Tier 1 to 5 (Expert and Challanger Tier)

I am open to any kind of feedback you guys have. If I missed a defender that works great on any specific node, please let me know by comment.

Note: There are many champions that I have not mentioned. All the champions I didn’t mention are not good defenders, but let me know if I missed any good ones. If you are trying to maintain diversity, feel free to use them after you have covered all defenders mentioned in the list.

Path 1

NodeBuffsSuggested Defenders
4Reinvigorated (Fury)
Personal Space – Regen
Indomitable

Wolverine Weapon X
Sauron
Hulking

13Reinvigorated (Fury)
Masochism Over Time
Indomitable
Mister Sinister
Toad

Magik
30Reinvigorated (Unblockable)
Never Back Down
Indomitable
Apocalypse
Darkhawk
Iron Man Infinity War
40Reinvigorated (Unblockable)
Buffet Over Time
Indomitable
Man-Thing
Bishop
Sorcerer Supreme

Path 2

NodeBuffsSuggested Defenders
5Drip Feed – Placebo
Roll with the punches
Shatter
Rintrah
Symbiote Supreme
Man-Thing
Scarlet Witch (OG)
14Combat Deja vu – Placebo
Nullify Countdown
Rintrah
Ebony Maw
Spider-Man Supreme
31Personal Space – Placebo
Subterfuge – Knockdown
Dr. Strange
Purgatory
Spider-Man Supreme
41Personal Space – Placebo
EMP Modification
Longshot
Sorcerer Supreme

Path 3

NodeBuffsSuggested Defenders
6Electric Defense
Spaced Armor
Backboard Brawler
Opportunist
Omega Sentinel
Colossus
Nimrod
15Electric Defense
Spaced Armor
Heavy Handed
Infamous Iron Man
Psycho Man
Guardian
32Slopped Armor
Chitinous Thorns
Enhanced Bleed
Omega Sentinel
Silver Centurion

Warlock
42Slopped Armor
Static Defense
Enhanced Shock
Hulkbuster
Red Skull
Ultron (OG)

Path 4

NodeBuffsSuggested Defenders
1Steady Buildup – Fury
Running on Fumes
While They’re Down
Heal Block
Void
Black Widow Claire Voyant

Scorpian
10Steady Buildup – Fury
Long-Distance Relationship
Insult to Injury
Kitty Pryde
Iron Man Infinity War
Annihilus
27Steady Buildup – Unblockable
Spry
Knull
Mister Fantastic
Invisible Woman
War Machine
36Steady Buildup – Unblockable
Crumbling Armor
Havok
Knull

Path 5

NodeBuffsSuggested Defenders
2
Ebb and Flow – Knock Down
Right Back At It
Force of Will
Hit Monkey
Darkhawk
Daredevil (H.K.)
11Ebb and Flow – Knock Down
Heavy Hitter
Nick Fury
Misty Knight
Mole-Man
Iron Man Infinity War
29
Ebb and Flow – Intercept
Sadist
Kitty Pryde
Rhino
Thor Ragnarok
37Ebb and Flow – Intercept
Mighty Charge
Mole-Man
Nova
Peni Parker

Path 6

NodeBuffsSuggested Defenders
3Combat Deja Vu – Prowess
Spiked Armor
Bishop
Domino
12Aggression: Prowess
Critical Setup
Ebony Maw
Sersi
28Prowess Build-up – Unblockable
Superior Special
Return Policy
Sauron
Apocalypse
Magneto (White)
Cable
Storm (Pyramid X)
38Prowess Build-up – Unblockable
Passively Special
Hard Knock Life
Void
Bishop
Nick Fury

Path 7

NodeBuffsSuggested Defenders
7Conflictor
Power Efficiency
Peni Parker
Iron Man Infinity War
Wong
16Energize
Brute Force
Vision (OG)
Vision (Aarkus)
Mangog
Wiccan
33Spite
Rise of Power
Havok
Domino
Infamous Iron Man
43Kinetic Transference
Aspect of Evolution
Quicksilver
Ebony Maw

Nick Fury
Blade
Agent Venom

Path 8

NodeBuffsSuggested Defenders
8Rich Gets Richer (Fury)
Feats of Power

Mystic Ward
Super Skrull
Silver Surfer
17Rich Gets Richer (Fury)
Personal Space
Mystic Ward
Venom
Crossbones
White Magneto
34Rich Gets Richer (Power)
Enhanced Parry (Armored UP)
Mystic Ward
Omega Sentinel
Gorr
Odin
Nova
44Rich Gets Richer (Power)
Opportunist
Mystic Ward
Infamous Iron Man
Black Panther CW
Captain America Sam Wilson

Path 9

NodeBuffsSuggested Defenders
9
Shifting Hazards – Incinerate/poison
Schadenfreude
Vision Aarkus
Havok
Mister Negative
18Shifting Hazards – Incinerate/poison
Feet of Indestructible
Power Focus
Purgatory
Bishop
Sauron
Peni Parker
Scorpion
35Hazard Shift – Shock and Bleed
One Eye Open
Peni Parker
Magneto
Spider-Ham
Dragon Man
45Hazard Shift – Shock and Bleed
Nerve of Steel
Mole-Man
Thing
Nimrod
Kitty Pryde
Knull

Middle Nodes (Intersection Nodes)

NodeBuffsSuggested Defenders
20Strike Counter – Fury
Spaced Armor
Masochism Over Time
Gorr
Man-Thing
19Ebb and Flow – Knockdown
Right Back At It
Aggression: Prowess
Darkhawk
America Chavez
Mister Negative

21Hazard Shift – Incinerate, poison
Schadenfreude 

Power Efficiency
Kraven
Black Cat
Misty Knight
Elsa Bloodstone
22Hazard Shift – Incinerate, Shock
Aggression – Prowess
Insult To Injury
Thing
Wolverine Weapon X
23Scared Stiff
Power Focus
Bubble Shield
Kraven
Nick Fury
Quicksilver
24Slopped Armor
Buffet Over Time
Vigorous Assault
Infamous Iron Man
Omega Sentinel
Captain America Sam Wilson
Warlock
25Prowess Build-Up – Unblockable
Power Snack
One too many hits
Kitty Pryde
Sauron
Bishop
26Hazard Shift – Shock, Bleed
Conflictor
Crumbling Armor
Void
Apocalypse
46Strike Counter – Block Penetration
Outlast
Never Back Down
Slopped Armor
Apocalypse
Knull
Annihilius
39Ebb and Flow – Intercept
Mighty Charge
Crumbling Armor
Titania
Spot
Kitty Pryde
47Rich Get Richer
Aspect of Evolution
Mystic Ward
Personal Space – Fury
Venom
Omega Sentinel
Galan
Hulking

Mini-Bosses and the Boss

NodeBuffsSuggested Defenders
48Feat of Vigilance
Power Efficiency
Missing in Action
Return Policy
Super Skrull
Silver Surfer
Omega Sentinel
49Shifting Hazards – Incinerate/poison
Debilitate
Stun Immunity
Peni Parker
Vision Aarkus
Air Walker
Korg
50Increased Recovery
Safeguard

Indomitable
Vigorous Assault
Hulking
Gorr
Wolverine Weapon X
Man-Thing
51Combat Deja Vu-Prowess
Prowess Puncture 
Conflictor
Bishop
Apocalypse
53Stunning Reflection
Polka Dot Power
Stun Vulnerability
Stupify
Kitty Pryde
Thing
Black Cat
 
54Aspect of Evolution
Special 2 Bias
Unblockable Sp2

Improved Power Gain 100%
Vision (Classic)
Mangog
America Chavez
Vision Aarkus

Doom
Longshot
55The Best Defense
Brute Force
Hard knock life

Limber
Peni Parker
Kitty Pryde
Spot
52Stun Immune
True Strike
Adaptive
Boss Node – Check Boss Suggestion-
at the top of the page

Alliance War Defender Suggestion – Tier 6 to 9 (Hard Tier)

Path 1

NodeBuffsSuggested Defenders
4Reinvigorated (Fury)
Arc Overload
Gorr
Hulking
Galan
13Reinvigorated (Fury)
Masochism Over Time
Mister Sinister
Toad

Magik
30Reinvigorated (Unblockable)
Never Back Down
Indomitable
Apocalypse
Darkhawk
Iron Man Infinity War
40Reinvigorated (Unblockable)
Buffet Over Time
Man-Thing
Bishop
Sorcerer Supreme

Path 2

NodeBuffsSuggested Defenders
5Drip Feed – Placebo
Shatter
Rintrah
Symbiote Supreme
Man-Thing

Scarlet Witch (OG)
14Combat Deja vu – Placebo
Nullify Countdown
Rintrah
Ebony Maw
Spider-Man Supreme
31Personal Space – Placebo
Power Draw
Man-Thing
Warlock
Spider-Man Supreme
41Personal Space – Placebo
Subterfuge – Special
Longshot
Sorcerer Supreme

Path 3

NodeBuffsSuggested Defenders
6Electric Defense
Spaced Armor
Backboard Brawler
Omega Sentinel
Colossus
Nimrod
15Electric Defense
Spaced Armor
Heavy Handed
Infamous Iron Man
Psycho Man
Guardian
32Slopped Armor
Chitinous Thorns
Omega Sentinel
Silver Centurion

Warlock
42Slopped Armor
Static Defense
Enhanced Shock
Hulkbuster
Red Skull
Ultron (OG)

Path 4

NodeBuffsSuggested Defenders
1Steady Buildup – Fury
Caltrops
Void
Scorpian
Doctor Doom
10Aggression – Fury
Toxicant? Toxi-Can
Apocalypse
Iron-Man IW
Quicksilver
27Steady Buildup – Unblockable
Fissure
Invisible Woman
Quicksilver
War Machine
36Steady Buildup – Unblockable
Long Distance Relationship
Knull
Mister Fantastic

Path 5

NodeBuffsSuggested Defenders
2
Aegis(Heavy)
Right Back At It
Darkhawk
Infamous Iron Man
11Aegis(Heavy)
Sadist
Ebony Maw
Mister Negative
29
Buff Toggle (Unstopple)
Sadist
Peni Parker
Domino
37Buff Toggle (Unstopple)
Limber
Kitty Pride
Hulking

Path 6

NodeBuffsSuggested Defenders
3Combat Deja Vu – Prowess
Prowess Puncture
Apocalypse
Sersi
Bishop
Domino
12Aggression: Prowess
Special 2 Bias
Bishop
Galan
Ikaris
Nova
Doctor Doom
Kingpin
28Prowess Build-up – Unblockable
Superior Special
Return Policy
Sauron
Apocalypse
Magneto (White)
Cable
Storm (Pyramid X)
38Prowess Build-up – Unblockable
Passively Special
Hard Knock Life
Void
Bishop
Nick Fury

Path 7

NodeBuffsSuggested Defenders
7Conflictor
Supercharge
Peni Parker
Thing

Bishop
16Energize
Brute Force
Nimrod
Rintrah
Vision (Aarkus)

Vision (Classic)
Mangog
Wiccan
33Spite
Rise of Power
Havok
Domino
Infamous Iron Man
43Kinetic Transference
Aspect of Evolution
Quicksilver
Ebony Maw

Nick Fury
Blade
Agent Venom

Path 8

NodeBuffsSuggested Defenders
8Rich Gets Richer (Fury)
Feats of Power

Mystic Ward
Hyperion
Super Skrull
Silver Surfer
17Rich Gets Richer (Fury)
Feats of Vigilance
Mystic Ward
Venom
Crossbones

Hulking
White Magneto
34Rich Gets Richer (Power)
Enhanced Parry (Armored UP)
Mystic Ward
Omega Sentinel
Gorr
Odin
Nova
44Rich Gets Richer (Power)
Opportunist
Mystic Ward
Infamous Iron Man
Black Panther CW
Captain America Sam Wilson

Path 9

NodeBuffsSuggested Defenders
9
Biohazard
While They Are Down
Knull
Quicksilver
Mister Fantasic
18Biohazards
Insult to Injury
Void
Vision Arkus
Mole-Man
35Hazard Shift – Shock and Bleed
Limber
Peni Parker
Magneto
Spider-Ham
Dragon Man
45Hazard Shift – Shock and Bleed
Nerve of Steel
Mole-Man
Thing
Nimrod
Kitty Pryde
Knull

Middle Nodes (Intersection Nodes)

NodeBuffsSuggested Defenders
20Strike Counter – Fury
Spaced Armor
Masochism Over Time
Gorr
Man-Thing
19Ebb and Flow – Knockdown
Right Back At It
Aggression: Prowess

Darkhawk
America Chavez
Mister Negative

21Hazard Shift – Incinerate, poison
Schadenfreude 

Supercharge
Kraven
Black Cat
Misty Knight
Elsa Bloodstone
22Hazard Shift – Incinerate, Shock
Aggression – Prowess
Insult To Injury
Thing
Wolverine Weapon X
23Scared Stiff
Power Focus
Bubble Shield
Kraven
Nick Fury
Quicksilver
24Slopped Armor
Buffet Over Time
Vigorous Assault
Infamous Iron Man
Omega Sentinel
Captain America Sam Wilson
Warlock
25Prowess Build-Up – Unblockable
Power Snack
One too many hits
Kitty Pryde
Sauron
Bishop
26Hazard Shift – Shock, Bleed
Conflictor

Crumbling Armor
Void
Apocalypse
46Strike Counter – Block Penetration
Outlast
Never Back Down
Apocalypse
Knull
Annihilius
39Buff Toggle (Unstoppable)
Limber
Crumbling Armor
Killmonger
Hulking
47Rich Get Richer
Mystic Ward
Personal Space – Fury
Venom
Omega Sentinel
Galan
Hulking

Mini-Bosses and the Boss

NodeBuffsSuggested Defenders
48Feat of Vigilance
Power Efficiency
Missing in Action
Super Skrull
Silver Surfer
Omega Sentinel
Hyperion
49Shifting Immunities (Bleed/Poison)
Limber
Peni Parker
Vision Aarkus
Air Walker
Korg
50Increased Recovery
Safeguard

Indomitable
Hulking
Gorr
Wolverine Weapon X
Man-Thing
51Combat Deja Vu-Prowess
Prowess Puncture 
Conflictor
Bishop
Apocalypse
53Shifting Immunities (Bleed/Poison)
Polka Dot Power
Kitty Pryde
Thing
Black Cat

Warlock
54Aspect of Evolution
Special 2 Bias
Improved Power Gain 100%
Vision (Classic)
Mangog
America Chavez
Vision Aarkus

Doom
Longshot
55Bane
Hard knock life

Limber
Peni Parker
Kitty Pryde
Spot
52Stun Immune
True Strike
Adaptive
Boss Node – Check Boss Suggestion-
at the top of the page

Alliance War Defender Suggestion – Tier 10 to 12 (Intermediate Tier)

Path 1

NodeBuffsSuggested Defenders
4Reinvigorated (Fury)Gorr
Hulking
Galan
13Reinvigorated (Fury)Mister Sinister
Toad

Magik
30Reinvigorated (Unblockable)Apocalypse
Darkhawk
Iron Man Infinity War
40Reinvigorated (Unblockable)Man-Thing
Spider-Man (Supreme)
Sorcerer Supreme

Path 2

NodeBuffsSuggested Defenders
5Drip Feed – Placebo
Shatter
Rintrah
Symbiote Supreme
Man-Thing

Scarlet Witch (OG)
14Combat Deja vu – Placebo
Nullify Countdown
Rintrah
Ebony Maw
Spider-Man Supreme
31Personal Space – PlaceboMan-Thing
Warlock
Spider-Man Supreme
41Personal Space – PlaceboLongshot
Sorcerer Supreme

Path 3

NodeBuffsSuggested Defenders
6Electric Defense
Backboard Brawler
Omega Sentinel
Colossus
Nimrod
15Electric Defense
Heavy Handed
Infamous Iron Man
Psycho Man
Guardian
32Slopped Armor
Chitinous Thorns
Omega Sentinel
Silver Centurion

Warlock
42Slopped Armor
Static Defense
Hulkbuster
Red Skull
Ultron (OG)

Path 4

NodeBuffsSuggested Defenders
1Aggression – FuryIron-Man IW
Spot
10Aggression – FuryApocalypse
Silver Centurian
27Steady Buildup – UnblockableInvisible Woman
Quicksilver
War Machine
36Steady Buildup – UnblockableKnull
Mister Fantastic

Havok

Path 5

NodeBuffsSuggested Defenders
2
EBB and Flow (Knock Down)
Aggression Prowess
Darkhawk
Daredevil (H.K.)
11Aegis(Heavy)Ebony Maw
Mister Negative
29
SafeguardGorr
Peni Parker
Hulking
Sauron
37Safeguard 1%
Limber
Misty Knight
Black Cat
Nick Fury

Path 6

NodeBuffsSuggested Defenders
3Combat Deja Vu – ProwessApocalypse
Sersi
Bishop
Domino
12Aggression: ProwessBishop
Storm (Both)
Galan
28Prowess Build-up – Unblockable
Superior Special 1
Sauron
Apocalypse
Magneto (White)
Cable
Storm (Pyramid X)
38Prowess Build-up – Unblockable
Hard Knock Life
Void
Bishop
Nick Fury

Path 7

NodeBuffsSuggested Defenders
7ConflictorPeni Parker
Thing

Bishop
16Energize 50%Vision (Aarkus)
Vision (Classic)
Mangog
Wiccan
33SpiteHavok
Domino
Infamous Iron Man
43Kinetic TransferenceQuicksilver
Ebony Maw

Nick Fury
Blade
Agent Venom

Path 8

NodeBuffsSuggested Defenders
8Rich Gets Richer (Fury)
Mystic Ward
Hyperion
Super Skrull
Silver Surfer
17Rich Gets Richer (Fury)
Mystic Ward
Venom
Crossbones

Hulking
White Magneto
34Rich Gets Richer (Power)
Enhanced Parry (Armored UP)
Mystic Ward
Omega Sentinel
Gorr
Odin
Nova
44Rich Gets Richer (Power)
Mystic Ward
Infamous Iron Man
Black Panther CW
Captain America Sam Wilson

Path 9

NodeBuffsSuggested Defenders
9
BiohazardDoom
Thing
Void
18Biohazards
Feats of Indestructible 1
Vision Arkus
Mole-Man
35Hazard Shift – Shock and BleedPeni Parker
Magneto
Spider-Ham
Dragon Man
45Hazard Shift – Shock and BleedMole-Man
Thing
Nimrod
Kitty Pryde
Knull

Middle Nodes (Intersection Nodes)

NodeBuffsSuggested Defenders
20Strike Counter – Fury
Spaced Armor
Gorr
Man-Thing
19Ebb and Flow – Knockdown
Bubble Shield
Darkhawk
America Chavez
Mister Negative
21Biohazard
Schadenfreude 
Knull
Kraven
22Hazard Shift – Incinerate, Shock
Aggression – Prowess
Thing
Wolverine Weapon X
23Scared Stiff
Power Focus 2
Kraven
Ikaris
Wiccan
Quicksilver
24Slopped Armor
Buffet Over Time
Infamous Iron Man
Omega Sentinel
Captain America Sam Wilson
Warlock
25Prowess Build-Up – Unblockable
Power Snack
Kitty Pryde
Sauron
Bishop
26Hazard Shift – Shock, Bleed
Conflictor
Void
Apocalypse
46Strike Counter – Block Penetration
Outlast
Apocalypse
Knull
Annihilius
39Buff Toggle (Unstoppable)
Limber
Killmonger
Hulking
Domino
Mole Man
Hyperion
47Rich Get Richer
Mystic Ward
Personal Space – Fury
Venom
Omega Sentinel
Galan
Hulking

Mini-Bosses and the Boss

NodeBuffsSuggested Defenders
48Feat of Vigilance
Kinetic Reactor
Missing in Action
Super Skrull
Silver Surfer
Omega Sentinel
Hyperion
49Shifting Immunities (Bleed/Poison)Peni Parker
Vision Aarkus
Air Walker
Korg
50Increased Recovery
Safeguard
Hulking
Gorr
Wolverine Weapon X
Man-Thing
51Combat Deja Vu-Prowess
Prowess Puncture 2
Bishop
Apocalypse
53Polka Dot PowerKitty Pryde
Elsa Bloodstone
Jabari Panther
54Aspect of Evolution
Improved Power Gain
Vision (Classic)
Mangog
America Chavez
Vision Aarkus

Doom
Longshot
55Bane
The Beast Defense
Peni Parker
Kitty Pryde
Spot
52Stun Immune
True Strike
Adaptive
Boss Node – Check Boss Suggestion-
at the top of the page

I am open to any kind of feedback you guys have. If I missed a defender that works great on any specific node, please let me know by comment.

Note: There are many champions that I have not mentioned. All the champions I didn’t mention are not good defenders, but let me know if I missed any good ones. If you are trying to maintain diversity, feel free to use them after you have covered all defenders mentioned in the list.